Iodometry, also known as iodometric titration, is a method of volumetric chemical analysis, involves indirect titration of iodine liberated by reaction with the analyte, whereas iodimetry involves direct titration using iodine as the titrant. What is the Difference Between Iodometry and Iodimetry? In Iodometry two redox reactions occur. In Iodimetry, only one redox reaction process. Iodometry and Iodimetry – Download as Word Doc .doc /.docx), PDF File .pdf), Text File .txt) or read online.

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Difference Between Iodometry and Iodimetry

Iodometry iodimtery iodimetry are two common titration methods useful in analytical chemistry. Examples include the determination of copper IIchlorateHydrogen peroxideand dissolved oxygen:.

Safety in the laboratory. One reaction is involved.

Difference Between Iodometry and Iodimetry l Iodometry vs Iodimetry

The analytical chemistry laboratory. This makes analysis of hexacyanoferrate III troublesome as the iodide and thiosulfate decomposes in strongly acidic medium. The free form either as a gas or an acid is the most important because it inhibits the action of microoganisms and acts as an antioxidant.

This titrating species is a standard ildometry of a reducing agent, which is capable of reducing iodine back to iodide form.

Note that for the best results, the sulfide solution must be dilute with the sulfide concentration not greater than 0.

A direct titration with only 1 reaction: Iodimetry is less common when compared to Iodometry. A titration is a procedure in which volume increments of the known reagent solution-which is called the titrant- are added to the analyte until the reaction is complete.



Introduction to iodometric and iodimetric titrations Examples Acid-base Quantification of acetic acid in vinegar Complexometric Precipitation Redox Slide 4: This is one difference between iodometry and iodimetry. In iodimetry, it uses iodometry iodine to undergo titration with a reducing agent. Once the bond between the iodine I 2 and the helical chain of beta-amylose is formed it turns an intense blue. Usually, we use a standard thiosulphate solution for this.

Reaction of radicals responsible for formation of hydroperoxides in edible fats and oils. Pre-treatment of the sample.

This suspension is a watery solution of starch with a few drops of bactericide added to prevent decomposition, as this would stop the starch behaving as an indicator. Moreover, we can use iodine for this redox titrations due to its capability of reacting iodlmetry with many species. The key difference between iodometry and iodimetry is that we can use Iodometry to quantify oxidizing agentswhereas we can use iodimetry to quantify reducing agents.

You also know that an analyte is the substance being analyzed. With a mind rooted firmly to basic principals of chemistry and passion for ever evolving field of industrial chemistry, she is keenly interested to be a true companion for those who seek knowledge in the subject of chemistry.

Application of Iodometry In the food industry, iodometry is widely used to determine the concentration of hydroperoxides in any given lipid matrix oils and fats for human consumption. What happens here is, an excess amount of Iodide solution typically Potassium Iodide is mixed with iidometry sample of the water that needs to be tested.


Determining the concentration of these chemicals is important because hydroperoxides have a negative effect on the acceptability of the fat matrix used, and on the food fried in it, and iodimetrg also decompose easily, forming molecules which are dangerous for human health. The iodine content and thus the active chlorine content can be determined with iodometry.

Therefore, by determining the end point of the reaction, equations can be derived to obtain information of the stoichiometry and other necessary relationships between the reducing agent and Iodine which acts as the oxidizing agent in this case. Do you remember other redox titrations that we have done in the laboratory? Iodine I2 Iodometric titrations: The half-reaction is as follows: Sulphur dioxide has several important functions: Neutralisation titration – part two Then we can titrate the released iodine with another species.

In the presence of I- ions the starch solution is colourless. iodometrry

Iodometry and Iodimetry, Daniele Naviglio « Analytical Chemistry « Agraria « Federica e-Learning

Instrumental Chemical Analysis Introduction to iodometric and iodimetric titrations An oxidaizing agent is the element or compound in a redox reaction that oxidaizes another species. Optical methods of analysis The substance of a known concentration is called the titrant.

In iodometry, iodides react with another oxidizing agent in an acidic medium or neutral medium.